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the end of Sultans of Swing by Dire Straits.

most of Joe Bonamassa is pretty good, he's a blues guitar player, with a slight metal influence.

also, pretty much any Lynyrd Skynyrd, they are awesome.

I don't think anybody's said Simple Man, but that's got a good one too. The multiple guitars in unison just has somethign about it that sends shivers down your spine.

The Outlaws- "Green Grass and High Tides"

Yes - "Starship Trooper" live version.

Molly Hatchet - "Flirtin With Disaster"

to name some more that always have good guitar,

Albert King, BB King, Buddy Guy, Eric Clapton, Allman Brothers (these bands are more blues guitar, which I think is better than metal personally) and there are always more...

EDIT: The Eagles, and the Doobie Brothers.